Effects of annealing temperature on TiO2 photoelectrodes of dye-sensitized solar cells using Ixora coccenia dye extract

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作者
Emmanuel O. Onah
M. A. Onuorah
S. U. Offiah
Raphael M. Obodo
O. V. Ekechukwu
P. E. Ugwuoke
Fabian I. Ezema
机构
[1] University of Nigeria,Department of Physics and Astronomy
[2] National Center for Physics,NPU
[3] Northwestern Polytechnical University,NCP Joint International Research Center On Advanced Nanomaterials and Defects Engineering
[4] Nanosciences African Network (NANOAFNET) iThemba LABS-National Research Foundation,UNESCO
[5] University of South Africa (UNISA),UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies
[6] University of Nigeria,Department of Mechanical Engineering
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关键词
Dye; Crystallite size; Doctor Blade; DSSC; Grain size; Efficiency; Nanostructures;
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摘要
Ixora coccinea flower was utilized as source of natural dye to fabricate dye sensitized solar cells (DSSCs) using TiO2 electrodes. The electrodes were fabricated using Doctor Blade’s method and annealed at 600 °C, 450 °C, and 300 °C. The structural, morphological, and elemental composition analyses of the TiO2 electrodes were carried out. The dye extract and the TiO2 electrodes had low absorbance within the visible region of electromagnetic spectrum. The TiO2 photoanode annealed at 300 °C, 450 °C, and 600 °C had crystallite sizes of 26.52, 24.36, and 21.85 nm and average grain sizes of 85 nm, 169 nm, and 184 nm in that order. The DSSC fabricated based on the Ixora coccinea flower dye extract revealed conversion efficiency of 0.73%, 1.18%, and 1.01% for the TiO2 electrodes annealed at 300 °C, 450 °C, and 600 °C respectively.
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