Chemiluminescence during thermal degradation of sodium persulfate in the presence of terbium sulfate: 1. The catalytic effect of terbium(III) ions

被引：0
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作者：
A. A. Mamykin
A. V. Mamykin
V. A. Antipin
V. P. Kazakov
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center
来源：
High Energy Chemistry | 2009年 / 43卷
关键词：
Thermal Degradation; Persulfate; Terbium; High Energy Chemistry; Chemiluminescence Intensity;
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摘要：
Chemiluminecscence (CL) generated during the thermal degradation of sodium persulfate in the presence of terbium(III) sulfate was studied. The CL spectrum corresponds to emission from excited terbium ions. It was found that Tb(III) acts not only as a photon emitter but also a catalyst for the thermal degradation of sodium persulfate. A scheme of reactions resulting in the formation of excited-state Tb(III) was proposed.
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页码：496 / 498
页数：2
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