Thermodynamic functions of the mixing of methacrylic acid in organic solvents

被引:0
|
作者
V. V. Sergeev
Yu. V. Kos
机构
[1] Lviv Polytechnic National University,
来源
Russian Journal of Physical Chemistry A | 2017年 / 91卷
关键词
tensimetry; saturated vapor pressure; activity coefficients; excess functions of mixing; methacrylic acid; acetonitrile; benzene; hexane; 1,2-dichloroethane; acetic acid;
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摘要
The saturated vapor pressure over solutions of methacrylic acid is measured tensimetrically in acetonitrile, benzene, hexane, 1,2-dichloroethane, and acetic acid is measured tensimetrically at 290–350 K. The composition of equilibrium phases, the activity coefficients of the components, and the thermodynamic functions of the mixing (HE, GE, SE) of the investigated solutions are calculated from the temperature dependence data.
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页码:2131 / 2136
页数:5
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