Role of surface structures on the selective reduction of nitrogen oxides with hydrocarbons on oxide catalysts

被引：0
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作者：
V. A. Matyshak
V. F. Tret’yakov
机构：
[1] Russian Academy of Sciences,Semenov Institute of Chemical Physics
[2] Russian Academy of Sciences (IPS RAS),Topchiev Institute of Petrochemical Synthesis
来源：
Russian Journal of General Chemistry | 2009年 / 79卷
关键词：
General Chemistry; Nitrogen Oxide; Selective Catalytic Reduction; Transformation Rate; Apparent Rate Constant;
D O I：
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学科分类号：
摘要：
The infrared spectrum in situ was used to study the mechanism of selective reduction of nitrogen oxides on a series of oxide catalysts. It is shown that under the reaction conditions, nitrites, nitrates, and nitroorganic and acetate complexes are formed. Qualitative comparison of the rate of decomposition of the complexes and the rate of formation of the process products was performed using the spectral kinetic technique. Based on this comparison, the role of surface complexes in the process was determined. A mechanism showing the main stages of the reduction of nitrogen oxides is proposed.
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页码：1400 / 1411
页数：11
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