Redox Isomerism of α-Ferrocenylcarbenium Ions

被引：0
|
作者：
V. M. Fomin
K. S. Kochetkova
K. V. Klyuchevskii
机构：
[1] N.I. Lobachevskii State University of Nizhny Novgorod,
来源：
Russian Journal of General Chemistry | 2018年 / 88卷
关键词：
ferrocenylmethanol; vinylferrocene; protonation; α-ferrocenylcarbenium ion; ferrocenium cation; redox isomerism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The formation of α-ferrocenylcarbenium ions FcC+H2 (λmax 600 nm) and FcC+HCH3 (λmax 730 nm) and their redox isomerism at the protonation of ferrocenylmethanol and vinylferrocene was proved using the method of electronic spectroscopy. The effect on the process of the solvent and acid nature as well as of hydrogen peroxide additives is discussed.
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页码：948 / 953
页数：5
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