Synthesis of functionalized vinylpyridine-based phosphinic acids and their derivatives

被引：0
|
作者：
A. A. Prishchenko
M. V. Livantsov
O. P. Novikova
L. I. Livantsova
S. V. Baranin
Yu. N. Bubnov
机构：
[1] Lomonosov Moscow State University,N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2023年 / 72卷
关键词：
bis(trimethylsiloxy)phosphine; vinylpyridines; radical addition; azobis-(isobutyronitrile); aminomethylation; 2-carboxyethylation; pyridine derivatives; phosphinic acids; biologically active substances; polydentate ligands;
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学科分类号：
摘要：
Functionalized phosphinic acids bearing aminomethyl and 2-carboxyethyl groups were synthesized using vinylpyridines as the starting material. The radical addition of bis(trimethylsiloxy)phosphine to vinylpyridines proceeded regioselectively to give new (2-pyridinylethyl)phosphonites. The later were aminomethylated and 2-carboxyethylated to obtain the target phosphinic acids. The synthesized compounds are of interest as the promising biologically active substances and efficient ligands.
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页码：1576 / 1583
页数：7
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