Crystallization kinetics of amorphous

被引:0
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作者
K. Chrissafis
K. G. Efthimiadis
E. K. Polychroniadis
S. C. Chadjivasiliou
机构
[1] Aristotle University of Thessaloniki,Physics Dept.
关键词
crystallization; non-isothermal kinetics; activation energy; Fe-Si-B; DSC; model free kinetics;
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摘要
In this work we study the influence of Mo admixtures on the crystallization process of amorphous Fe78-xMoxSi9B13 (x=1, 2, 3 and 4) alloys by measurements of differential scanning calorimetry and on the soft ferromagnetic properties of the alloys by magnetic measurements. The addition of Mo by replacing Fe, results in magnetic hardening of materials. In DSC curves two peaks appear which are distinct when the concentration of Mo is 1 at.% and partly overlap when the Mo content is 2 at.%. Further increase in the Mo content leads to the appearance of just one peak. The activation energy was calculated both with Kissinger's and isoconversional Flynn, Wall and Ozawa methods.
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页码:761 / 767
页数:6
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