The effect of cathode material on nitric acid reduction kinetics

被引：0
|
作者：
V. P. Razygraev
M. V. Lebedeva
机构：
[1] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry
来源：
Protection of Metals and Physical Chemistry of Surfaces | 2014年 / 50卷
关键词：
nitric acid; boiling; reduction; autocatalysis; mechanism; chrome; stainless alloys; gold; tantalum; zirconium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The combined effect of potential and temperature on the mechanism of autocatalytic reduction of nitric acid is analyzed. The change of solubility of nitrogen oxides with temperature allows separation of potential intervals with predominant contribution of homogenous autocatalysis. Heterogeneous autocatalysis dominates in concentrated media, while homogenous catalysis is more real in totally disassociated solutions. The presence of nickel in steels catalyzes the formation of ammonia ions.
引用
收藏
页码：833 / 840
页数：7
相关论文
共 50 条
  • [1] The effect of cathode material on nitric acid reduction kinetics
    Razygraev, V. P.
    Lebedeva, M. V.
    [J]. PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2014, 50 (07) : 833 - 840
  • [2] The effect of cathode materials on the electrochemical reduction of nitric acid
    Vasudevan, D.
    [J]. POLISH JOURNAL OF CHEMICAL TECHNOLOGY, 2010, 12 (01) : 35 - 37
  • [3] EFFECT OF CATHODE MATERIAL AND ACID MEDIUM ON ELECTRIC REDUCTION OF TETRANITROMETHANE AND NITROMETHANE
    KUROCHKI.NA
    KEDRINSK.IA
    [J]. ZHURNAL PRIKLADNOI KHIMII, 1970, 43 (02) : 341 - +
  • [4] On the kinetics of the nitrate reduction in concentrated nitric acid
    Lange, Ronny
    Maisonhaute, Emmanuel
    Robin, Raphael
    Vivier, Vincent
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2013, 29 : 25 - 28
  • [5] KINETICS OF REACTION OF NITRIC ACID WITH ALUMINIUM .1. KINETICS OF DISSOLUTION OF ALUMINIUM IN NITRIC ACID AND OF REDUCTION OF LATTER
    GINDIN, LG
    DMITRENK.VE
    ZHERDEVA, TI
    SMIRENKI.IP
    FEDOROV, VV
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1971, 45 (02): : 240 - &
  • [6] Kinetics of Np(VI) reduction with carbohydrazide in nitric acid
    Zavalina O.A.
    Dvoeglazov K.N.
    Pavlyukevich E.Y.
    Stepanov S.I.
    [J]. Radiochemistry, 2017, 59 (5) : 453 - 457
  • [7] Kinetics of Pu(VI) Reduction with Diformylhydrazine in Nitric Acid
    Dvoeglazov K.N.
    Pavlyukevich E.Y.
    Mitrikas P.V.
    [J]. Radiochemistry, 2018, 60 (6) : 588 - 594
  • [8] Kinetics of Pu(VI) reduction with carbohydrazide in nitric acid
    Zavalina O.A.
    Dvoeglazov K.N.
    Pavlyukevich E.Y.
    [J]. Radiochemistry, 2017, 59 (04) : 331 - 336
  • [9] Kinetics of Np(VI) Reduction with Diformylhydrazine in Nitric Acid
    Dvoeglazov, K. N.
    Pavlyukevich, E. Yu.
    Mitrikas, P. V.
    [J]. RADIOCHEMISTRY, 2018, 60 (06) : 581 - 587
  • [10] Kinetics of reduction of hexavalent neptunium by nitrous acid in solutions of nitric acid
    Precek, Martin
    Paulenova, Alena
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2010, 286 (03) : 771 - 776
12345