Interrelation between the spatial structure of unsaturated hydrocarbon molecules and heats of their adsorption

被引：0

作者：

V. N. Serezhkin

M. A. Prokaeva

D. V. Pushkin

L. B. Serezhkina

S. Yu. Kudryashov

机构：

[1] Samara State University,

来源：

Russian Journal of Physical Chemistry A, Focus on Chemistry | 2008年 / 82卷

关键词：

Hydrocarbon; Phenanthrene; Adamantane; Saturated Hydrocarbon; Pentacene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The total area (sm) of Voronoi-Dirichlet polyhedron faces corresponding to all intermolecular contacts of one molecule in the structure of crystals and the total volume of pyramids (Vm) built on such faces and containing the nuclei of atoms participating in intermolecular contacts in their vertices were determined for 19 unsaturated hydrocarbons. The differential molar heat of adsorption of the hydrocarbons on graphitized thermal carbon black was found to be linearly related to the sm or Vm integral parameters of their Voronoi-Dirichlet polyhedra. Aromatic hydrocarbons on the one hand and saturated hydrocarbons, olefins, and acetylene on the other are characterized by different dependences because of the special shapes of their molecular Voronoi-Dirichlet polyhedra.

引用

页码：1349 / 1356

页数：7

共 50 条

[1] Interrelation between the spatial structure of unsaturated hydrocarbon molecules and heats of their adsorption
Serezhkin, V. N.
Prokaeva, M. A.
Pushkin, D. V.
Serezhkina, L. B.
Kudryashov, S. Yu.
[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (08) : 1349 - 1356
[2] Correlation between the spatial structure of molecules of saturated hydrocarbons and their heats of adsorption
V. N. Serezhkin
M. A. Prokaeva
D. V. Pushkin
L. B. Serezhkina
L. A. Onuchak
[J]. Russian Journal of Physical Chemistry A, Focus on Chemistry, 2008, 82 : 1343 - 1348
[3] Correlation between the spatial structure of molecules of saturated hydrocarbons and their heats of adsorption
Serezhkin, V. N.
Prokaeva, M. A.
Pushkin, D. V.
Serezhkina, L. B.
Onuchak, L. A.
[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (08) : 1343 - 1348
[4] Calorimetric and isosteric heats of adsorption of substances with molecules of different electronic structure
Kuznetsov, B.V.
Tuan, Ninh Anh
Rachmanova, T.A.
[J]. Adsorption Science and Technology, 1989, 6 (01): : 27 - 34
[5] HEATS OF ADSORPTION OF SMALL MOLECULES ON LACTOSE
MCMULLIN, SL
BERNHARD, RA
NICKERSON, TA
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1975, 23 (03) : 452 - 458
[6] The lengths of the links of unsaturated hydrocarbon molecules
Coulson, CA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12): : 1069 - 1071
[7] On the calculation of the energy in unsaturated hydrocarbon molecules
Coulson, CA
[J]. PROCEEDINGS OF THE CAMBRIDGE PHILOSOPHICAL SOCIETY, 1940, 36 : 201 - 203
[8] The adsorption of trichlorinated hydrocarbon in the unsaturated zone
刘菲
刘明亮
何江涛
[J]. 岩石矿物学杂志, 2007, (06) : 549 - 552
[9] ON THE HEATS OF FORMATION AND POTENTIAL BARRIERS FOR THE INTERNAL ROTATION IN HYDROCARBON MOLECULES
ITO, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (10) : 2430 - 2435
[10] Interrelation between thermodynamic similarity numbers and topological characteristics of the structure of organic molecules
V. G. Uryadov
N. V. Aristova
E. N. Ofitserov
[J]. Russian Journal of Physical Chemistry A, 2007, 81 : 688 - 692

← 1 2 3 4 5 →