Dehydrogenation of cycloalkanes over noble metal catalysts supported on active carbon

被引:1
|
作者
Wataru Ninomiya
Yasuhiko Tanabe
Ken-Ichiro Sotowa
Toshiya Yasukawa
Shigeru Sugiyama
机构
[1] Mitsubishi Rayon Co. Ltd.,Corporate Research Laboratories
[2] The University of Tokushima,Department of Chemical Science and Technology, Faculty of Engineering
[3] Minamijosanjima,Department of Advanced Materials, Institute of Technology and Science
[4] The University of Tokushima,Department of Geosphere Environment and Energy, Center for Frontier Research of Engineering
[5] Minamijosanjima,undefined
[6] The University of Tokushima,undefined
[7] Minamijosanjima,undefined
来源
关键词
Pt/C; Pd/C; Tellurium; dehydrogenation; cycloalkanes;
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学科分类号
摘要
Dehydrogenation of decalin to naphthalene through tetralin and that of dicyclohexyl to biphenyl through phenylcyclohexane with Pt/C and Pd/C was investigated mainly under the liquid film state, in which the catalyst was just wet but not suspended and covered with a thin film of liquid substrate. To improve the catalytic activities, the effects of the addition of tellurium into Pd/C were investigated to reveal that the combination of tellurium, palladium and conjugated systems produced during the dehydrogenation of cycloalkames was important to the improvement of the activities.
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页码:663 / 668
页数:5
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