Synthesis and some physicochemical properties of the carbazine acid silyl esters

被引：0
|
作者：
A. D. Kirilin
L. O. Belova
M. V. Pletneva
V. D. Sheludyakov
A. A. Korlyukov
机构：
[1] Lomonosov Moscow State Academy of Fine Chemical Technology,
来源：
Russian Journal of General Chemistry | 2011年 / 81卷
关键词：
Pyrolysis; General Chemistry; Isocyanate; Pyrolysis Product; Bifurcate Hydrogen Bond;
D O I：
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中图分类号：
学科分类号：
摘要：
Structure of the dimethylcarbazine acid trimethylsilyl ether and pyrolysis of its derivative, the trimethylsilyl ester of N,N-dimethyl-N′-trimethylsilylcarbazine acid, were studied by the metods of X-ray diffraction and gas chromatography/mass spectrometry. The presence of the bifurcated hydrogen bonds between the trimethylsilyl dimethylcarbazinate molecules was detected. It was revealed why impossible to obtain dimethylaminoisocyanate even by the low-temperature pyrolysis.
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页码：2252 / 2256
页数：4
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