Synthesis of Aromatic Carboxylic Acids by Carbonylation of Aryl Halides in the Presence of Epoxide-Modified Cobalt Carbonyls as Catalysts

被引：0
|
作者：
V. P. Boyarskii
T. E. Zhesko
S. A. Lanina
机构：
[1] VNIINeftekhim Joint-Stock Company,
[2] Galar Research and Production Limited Liability Company,undefined
来源：
Russian Journal of Applied Chemistry | 2005年 / 78卷
关键词：
Ester; Cobalt; Carbonyl; Carboxylic Acid; Epoxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new procedure was developed for synthesis of aromatic and heteroaromatic acids and their derivatives (esters, salts) by carbonylation of the corresponding aryl halides. The acids are selectively formed in a high yield under very mild conditions. Highly active catalytic systems, base-containing alcoholic solutions of cobalt carbonyl modified with epoxides, were used to activate aryl halides.
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页码：1844 / 1848
页数：4
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