Controlled hydrothermal synthesis and excellent optical properties of two different kinds of CeO2 nanocubes

被引:0
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作者
Jinbo Ni
Juan Gao
Hui Wei
Xianya Geng
机构
[1] Anhui University of Science and Technology,School of Mathematics and Big Data
[2] Anhui University of Science and Technology,School of Mechanics and Optoelectronic Physics
关键词
CeO2; Oxygen Vacancy; Rugged Surface; Emission Intensity Increase; Cube Structure;
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摘要
The CeO2 nanocubes have been successfully synthesized via a facile hydrothermal method. X-ray diffractometer, scanning electron microscope, transmission electron microscope, X-ray photoelectron spectroscopy (XPS), Raman scattering and photoluminescence spectra were employed to characterize the samples. The results showed that the CeO2 nanocubes have a cubic fluorite structure and the rugged CeO2 nanocubes with an edge length of about 200 nm transformed into smooth one with an edge length of about 70 nm with the change of the surfactant. XPS and Raman analyses indicate that there are Ce3+ ions and oxygen vacancies in the surface of samples. Both of nanocubes exhibit similar emission peaks of photoluminescence at room temperature and the emission intensity increases with the increase of the concentration of oxygen vacancies.
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页码:11029 / 11033
页数:4
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