A novel one-dimensional supramolecular inclusion compound linked by hydrogen bonding interaction

被引:0
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作者
Rui-Lian Lin
Jing-Xin Liu
La-Sheng Long
Rong-Bin Huang
Lan-Sun Zheng
机构
[1] Anhui University of Technology,Institute of Molecular Engineering and Applied Chemistry, College of Chemistry and Chemical Engineering
[2] Xiamen University,State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry
关键词
Cucurbit[6]uril; Hydrogen bonding interaction; X-ray crystallography; Supramolecular compound;
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学科分类号
摘要
Crystal structure analysis shows the cucurbit[6]uril host and its tetrahydrofuran (THF) guest in the Pmn21 crystal lattice. The crystal data and refinement parameter for the title compound are: a = 14.027(3), b = 11.807(3), c = 16.760(4) Å, V = 2774.7(9) Å3. For Z = 2 and Mw = 1529.52, the calculate density Dcal = 1.825 g/cm3. Hydrogen bonding interaction assembled the adjacent {[La(H2O)6Cl](C4H8O@C36H36N24O12)}2+ cations into a novel one-dimensional superamolecular chain.
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页码:263 / 267
页数:4
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