Synthesis and structure of 2-(nitromethylene)-2H-1,4-benzothiazin-3(4H)-one

被引：0
|
作者：
V. M. Berestovitskaya
V. A. Tafeenko
S. V. Makarenko
K. D. Sadikov
I. V. Chernyshev
机构：
[1] Gertsen Russian State University,
[2] Lomonosov Moscow State University,undefined
来源：
Russian Journal of General Chemistry | 2006年 / 76卷
关键词：
Carbonyl; Carbonyl Group; Diffraction Data; Form Layer; Neighboring Layer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new representative of benzothiazines, (2Z)-2-(nitromethylene)-2H-1,4-benzothiazin-3(4H)-one, was synthesized, and its structure was studied. According to 1H NMR, IR, and UV spectral and X-ray diffraction data, the molecules are planar highly conjugated structures that exist in crystal as centrosymmetric dimers; the latter form layers overlapping with each other and held together by strong π-π interaction between the carbonyl groups of neighboring layers.
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页码：135 / 140
页数：5
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