Comportement thermique du polypropylene au cours du vieillissement

被引:1
|
作者
Kaloustian J. [1 ]
Antonetti P. [2 ]
Berrada A. [3 ]
Claire Y. [2 ]
Perichaud A. [2 ]
机构
[1] Laboratoire de Chimie Analytique, Faculté de Pharmacie, F-13385 Marseille Cedex 5
[2] Lab. de Chim. Macromoleculaire, Université de Provence, F-13331 Marseille Cedex 3
[3] U. Phys.-Chim. l'Environnement D., Université IBN Tofaïl, Fac. des Sci.-Kénitra, 14000 Kénitra
关键词
Aging; DTA-TG; Oxidation; Polypropylene;
D O I
10.1023/A:1010149607364
中图分类号
学科分类号
摘要
Several samples of polypropylene were studied by thermal analysis. The photo-oxidation and the aging of polypropylene films showed a mass loss more than 7% in heating from 20 to 220°C (5°C min-1), cooling to 20°C and reheating to 220°C. The authors observed also a decrease of the melting and crystallization temperatures. The non aged samples or these ones with preservatives are thermo-oxidised and presented an exothermic peak at about 200°C in DTA heating. The DTA-TG simultaneous apparatus is very useful in the study of polypropylene oxidation by making comparative trials according to a well definite procedure.
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页码:327 / 340
页数:13
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