Regulation of visible-light-driven photocatalytic degradation of Rhodamine B on BiOBr via zeta potential

被引:0
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作者
Chang-cun Tang
Yan-fen Fang
Xin-qiang Cao
Hai-lin Tian
Ying-ping Huang
机构
[1] China Three Gorges University,College of Biological and Pharmaceutical Sciences
[2] China Three Gorges University,China Engineering Research Center of Eco
[3] China Three Gorges University,environment in Three Gorges Reservoir Region, Ministry of Education
来源
关键词
BiOB; Photocatalytic activity; Zeta potential; Ethanol;
D O I
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中图分类号
学科分类号
摘要
In this paper, bismuth oxybromide (BiOBr) photocatalysts were synthesized in the presence of tetrabutylammonium bromide (TBAB) at the different volume fractions of ethanol/water and named as BiOBr0, BiOBr20, BiOBr50, BiOBr80 and BiOBr100, respectively. The samples were characterized and applied to the degradation of Rhodamine B (RhB) under visible-light irradiation (λ ≥ 420 nm). The results indicated that both TBAB and ethanol significantly affected the crystal phase, morphology and surface charge distribution of BiOBr. The exposed (110) faces of BiOBr with Bi3+ sites contributed to its photocatalytic activity via the enhanced separation of electrons and photogenerated holes as well as the better photo-stability. BiOBr50 showed the optimal activity for the photodegradation of RhB. Superoxide radical (O2·−) as the dominant active species was responsible for the degradation of RhB.
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页码:509 / 520
页数:11
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