Comb-Like Polymethylsiloxanes. Synthesis, Structure and Properties

被引：0
|
作者：
M. A. Obrezkova
A. A. Kalinina
I. V. Pavlichenko
N. G. Vasilenko
M. V. Mironova
A. V. Semakov
V. G. Kulichikhin
M. I. Buzin
A. M. Muzafarov
机构：
[1] N. S. Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences,
[2] A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences,undefined
[3] A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences,undefined
来源：
Silicon | 2015年 / 7卷
关键词：
Polycondensation; Polydimethylsiloxane; Comb-like polymethylsiloxanes; Polyfunctional matrix; Intrinsic viscosity;
D O I：
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中图分类号：
学科分类号：
摘要：
Comb-like polymethylsiloxanes consisting of a silsesquioxane backbone and dimethylsiloxane side chains were synthesized by means of the “grafting to” method using a linear polyfunctional matrix [SiMe(ONa)O]n and monofunctional oligomers (CH3)3Si[OSi(CH 3)2]nOCOCH3. The effects of architecture of the synthesized methylsiloxane polymers on their physicochemical properties, rheology, and behavior at the air–water interface were studied and compared with those for the linear analogue – polydimethylsiloxane.
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页码：177 / 189
页数：12
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