A novel dinuclear CuII complex based on flexible bis(triazole): Synthesis, structure and physical properties

被引：0
|
作者：
X.-J. Xu
X. Fang
H.-N. Yu
Z. Zhou
J. Wang
机构：
[1] Yancheng Teachers University,School of Chemistry & Environmental Engineering
来源：
Journal of Structural Chemistry | 2017年 / 58卷
关键词：
Cu(II) complex; 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-1,2,4-triazole); dinuclear; photocatalytic activity;
D O I：
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中图分类号：
学科分类号：
摘要：
New dinuclear copper(II) complex [Cu2(BTE)2(N3)4] (1) (BTE = 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-1,2,4-triazole)) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that complex 1 is a centrosymmetric dinuclear Cu(II) cluster unit with a Cu–Cu separation of 3.267(6) Å. In addition, complex 1 exhibits a high photocatalytic degradation activity for the degradation of rhodamine B.
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页码：1440 / 1442
页数：2
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