Stability and mobility of the endohedral metallofullerene of La@C82 in polycarbonate polymer films

被引:0
|
作者
V. K. Koltover
T. A. Parnyuk
V. P. Bubnov
E. É. Laukhina
Ya. I. Éstrin
É. B. Yagubskii
机构
[1] Russian Academy of Sciences,Institute of Problems in Chemical Physics
[2] Taras Shevchenko Kiev National University,undefined
来源
关键词
Polymer; Phase State; Polycarbonate; Chemical Stability; Polymer Film;
D O I
暂无
中图分类号
学科分类号
摘要
An La@C82-doped polymer (bisphenol-A polycarbonate) was prepared. EPR spectra of La@C82 in a solid polymer film and in a polycarbonate solution in o-dichlorobenzene were studied. The EPR spectrum shape of La@C82 was shown to be sensitive to the phase state of the polymer. La@C82 in the film was found to have a high chemical stability below the glass formation temperature, thus permitting one to use the polymer for the storage and study of endohedral metallofullerenes.
引用
收藏
页码:529 / 530
页数:1
相关论文
共 50 条
  • [1] Stability and mobility of the endohedral metallofullerene of La@C82 in polycarbonate polymer films
    Koltover, VK
    Parnyuk, TA
    Bubnov, VP
    Laukhina, EÉ
    Éstrin, YI
    Yagubskii, ÉB
    PHYSICS OF THE SOLID STATE, 2002, 44 (03) : 529 - 530
  • [2] Dipole dynamics in the endohedral metallofullerene La@C82
    Nuttall, CJ
    Hayashi, Y
    Yamazaki, K
    Mitani, T
    Iwasa, Y
    ADVANCED MATERIALS, 2002, 14 (04) : 293 - +
  • [3] Chemical Derivatization of Endohedral Metallofullerene La@C82 with Digermirane
    Akasaka, T.
    Kato, T.
    Nagase, S.
    Kobayashi, K.
    Tetrahedron, 52 (14):
  • [4] Photocurrent enhancement in conducting polymer device by doping with endohedral metallofullerene La@C82
    Fujii, A
    Umeda, T
    Shirakawa, T
    Akasaka, T
    Yoshino, K
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (4A): : 2254 - 2255
  • [5] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C82
    Takano, Yuta
    Yomogida, Akinori
    Nikawa, Hidefumi
    Yamada, Michio
    Wakahara, Takatsugu
    Tsuchiya, Takahiro
    Ishitsuka, Midori O.
    Maeda, Yutaka
    Akasaka, Takeshi
    Kato, Tatsuhisa
    Slanina, Zdenek
    Mizorogi, Naomi
    Nagase, Shigeru
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) : 16224 - 16230
  • [6] Chemistry of endohedral metallofullerene ions:: Structural determination of the La@C82 isomer
    Akasaka, T
    Wakahara, T
    Kondo, M
    Shirakura, S
    Maeda, Y
    Nagase, S
    Kobayashi, K
    Waelchli, M
    Yamamoto, K
    Kato, T
    Kako, M
    Nakadaira, Y
    Gao, X
    Van Caemelbecke, E
    Kadish, KM
    FULLERENES FOR THE NEW MILLENNIUM, 2001, 2000 (11): : 323 - 331
  • [7] A Co-Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C82 and a Nickel Porphyrin with High Electron Mobility
    Sato, Satoru
    Nikawa, Hidefumi
    Seki, Shu
    Wang, Lu
    Luo, Guangfu
    Lu, Jing
    Haranaka, Masayuki
    Tsuchiya, Takahiro
    Nagase, Shigeru
    Akasaka, Takeshi
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (07) : 1589 - 1591
  • [8] Electronic structure of hydroxylated La@C82 endohedral metallofullerene: implications on photovoltaic cells
    Cisneros-Garcia, Z. N.
    Alejandro Hernandez, David
    Tenorio, Francisco J.
    Rodriguez-Zavala, J. G.
    MOLECULAR PHYSICS, 2020, 118 (14)
  • [9] XAFS study of metallofullerene LA@C82
    Nomura, M.
    Nakao, Y.
    Kikuchi, K.
    Achiba, Y.
    Physica B: Condensed Matter, 1995, 208-209 (1-4):
  • [10] Chemical Modification of Endohedral Metallofullerene La@C82 with 3-chloro-3-phenyldiazirine
    Ishitsuka, Midori O.
    Enoki, Haruka
    Tsuchiya, Takahiro
    Slanina, Zdenek
    Mizorogi, Naomi
    Nagase, Shigeru
    Liu, Michael T. H.
    Akasaka, Takeshi
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (5-6) : 1124 - 1130