Kinetics and Mechanism of the Oxidative Regeneration of Carbonyl Compounds from Oximes by Pyridinium Fluorochromate

被引:0
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作者
Abhinav Bhandari
Pallavi Mishra
Kalyan K. Banerji
机构
[1] J.N.V. University,Department of Chemistry
关键词
Deoximination; chromium (VI); kinetics; mechanism;
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学科分类号
摘要
Oxidative deoximination of aldoximes and ketoximes by pyridium fluorochromate proceeds by nucleophilic attack of the chromate oxygen on the oxime carbon to give a cyclic intermediate in the rate-determining step.
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页码:343 / 347
页数:4
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