Synthesis of sulfur-containing heterocyclic compounds based on isothiocyanate derivatives of perfluoroolefins (review)

被引：9

作者：

Furin G.G. ^{[1
]}

Zhuzhgov E.L. ^{[2
]}

机构：

[1] N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk

[2] Novosibirsk State University, Novosibirsk

来源：

Chemistry of Heterocyclic Compounds | 2002年 / 38卷 / 2期

关键词：

3-methyl-2-methylamino-6-pentafluoroethyl-5-trifluoromethyl-3H-pyrimidine-; 4-thione; 4,5-dihydrothiazole derivatives; 6H-1,3-thiazine; Intramolecular cyclization; Nucleophilic addition; Nucleophilic reagents; perfluoro(3-isothiocyanato-2-methyl-2-pentene);

D O I：

10.1023/A:1015320822860

中图分类号：

学科分类号：

摘要：

The paper reviews data on the synthesis of heterocyclic compounds with perfluoroalkyl groups based on the reaction of thiocyanate and isothiocyanate derivatives of perfluoroolefins with mononucleophilic reagents (C-, O-, S-, P-, and N-nucleophiles). It was shown that such derivatives are prospective synthons for the production of 1,3-thiazoles and 1,3-thiazolines. The factors affecting the formation of the heterocyclic system are identified.

引用

页码：129 / 150

页数：21

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