Specific properties of dehydrogenation centers in supported platinum catalysts

被引:0
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作者
O. B. Belskaya
N. M. Ostrovskii
Yu. K. Demanov
机构
[1] Federal Scientific Center,Boreskov Institute of Catalysis
关键词
Platinum catalysts; dehydrogenation centers; specific properties;
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摘要
Cyclohexane dehydrogenation was used as a model reaction to study the dehydrogenation function of Pt/Al2O3 catalysts. Fresh and coked catalysts were tested in two ranges of reaction conditions: model conditions (T=280–340°C, P=1 atm) and the conditions used in the naphtha reforming process (T=420–460°C, P=15 atm). Intrinsic properties of the dehydrogenation active centers were found to be identical throughout the experimental conditions. The coke deposits only block a part of the active centers without their qualitative modification.
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页码:119 / 126
页数:7
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