Two-dimensional nickel(II) tetraaza macrocyclic complex linked by hydrogen bonds

被引：0
|
作者：
Ki-Young Choi
机构：
[1] Kongju National University,Department of Chemistry Education
来源：
Journal of Chemical Crystallography | 2002年 / 32卷
关键词：
Crystal structure; nickel(II) complex; tetraaza macrocycle; two-dimensional network;
D O I：
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摘要：
The complex [Ni(L)](PDC) ⋅ 2H2O (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16,4, 01.18,07.12]docosane; PDC = 3,5-pyrazoledicarboxylate) has been synthesized and characterized by X-ray crystallography. It crystallizes in the monoclinic system P21/c with a = 9.739(4) Å, b = 10.491(3) Å, c = 16.884(3) Å, β = 97.17(2)°, V = 1711.5(8) Å3, Z = 4. The coordination environment around the nickel(II) ion exhibits a slightly distorted square-plane with four secondary amines of the macrocycle. The title compound is interconnected to give a two-dimensional network through the hydrogen-bonding interactions.
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页码：537 / 540
页数：3
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