Production of tungsten via leaching of scheelite with sulfuric acid

被引:0
|
作者
H. Razavizadeh
A. Ershad langroudi
机构
[1] Iran University of Science and Technology,Department of Materials and Metallurgy Engineering
[2] Iran Polymer and Petrochemical Institute,Faculty of Processing
来源
关键词
Tungsten; Scheelite; Leaching;
D O I
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学科分类号
摘要
A new process for leaching scheelite ore consists of leaching low- and high-grade concentrates with H2SO4 in the presence of H3PO4 and NaCl at atmospheric pressure. The resulting tungstic acid solution is then evaporated to produce ammonium paratungstate (APT): (NH4)10H2W12O42·4H2O. To obtain the yellow oxide (WO3), the APT is heated at 600° to 700°C for one hour to evaporate ammonia and water. The reduction of tungsten trioxide with H2 can be controlled by the temperature, time and water vapor partial pressure to produce α-W.
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页码:67 / 72
页数:5
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