Trends in the sulfuric acid-catalyzed consumption of styrene epoxide in an alcohol medium

被引：0
|
作者：
L. V. Petrov
V. M. Solyanikov
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 2022年 / 71卷
关键词：
oxidation; catalysis; oxygen; sulfuric acid; styrene epoxide; benzaldehyde; -butyl alcohol;
D O I：
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摘要：
The kinetics of consumption of styrene epoxide (2) and accumulation of benzaldehyde (3) catalyzed by sulfuric acid (1) in an alcohol medium was studied in a bubbling glass reactor in an oxygen atmosphere. The dependences of the rates of consumption of 2 and accumulation of 3 on the concentrations of reactants 1 and 2 are of the same type: V2 = k2[1]1[2]0, V3 = k3[1]1[2]0. Data indicating an important role of the anions of acid catalysts in the conversions of epoxides were obtained.
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页码：2138 / 2141
页数：3
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