Oxidative Cyclization of Lithium 4-Ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate

被引：0
|
作者：
N. S. Boltacheva
P. A. Slepukhin
V. I. Filyakova
V. N. Charushin
机构：
[1] Russian Academy of Sciences,Postovskii Institute of Organic Synthesis, Ural Branch
来源：
Russian Journal of Organic Chemistry | 2019年 / 55卷
关键词：
lithium 4-ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate; manganese(III) acetate; diethyl 2,5-dihydroxy-2,5-bis(trifluoromethyl)tetrahydrofuran-3,4-dicarboxylate; crystal structure; X-ray analysis;
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学科分类号：
摘要：
Diethyl 2,5-dihydroxy-2,5-bis(trifluoromethyl)tetrahydrofuran-3,4-dicarboxylate has been synthesized for the first time by reaction of lithium 4-ethoxy-1,1,1-trifluoro-4-oxobut-2-en-2-olate with manganese(III) acetate. The structure of its (2S*3S*4S*5S*) stereoisomer has been confirmed by X-ray analysis.
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页码：883 / 885
页数：2
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