Paradigms and Paradoxes Are Acyl Azides Resonance Stabilized?

被引：0
|
作者：
Joel F. Liebman
机构：
[1] University of Maryland,Department of Chemistry and Biochemistry
来源：
Structural Chemistry | 1999年 / 10卷
关键词：
Acyl azides; Curtius rearrangement; enthalpy of formation; enthalpy of reaction; phenyl/vinyl thermochemical equivalence, resonance energy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
By means of the generic isodesmic reaction C6H5COX + RCH3 → C6H5COCH3 + RX, the phenyl/vinyl thermochemical equivalence, and an experimental determination of the enthalpy of the Curtius rearrangement of acryloyl azide, the resonance energy of acyl azides was ascertained to be ca. 29 kJ mol−1.
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页码：327 / 329
页数：2
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