Crystal structure and fluorescence of a new 2D layered cadmium(II) malate coordination polymer

被引:0
|
作者
G. Cui
G. Dong
X. Liu
Ya. Yu
机构
[1] Hebei Polytechnic University,College of Chemical Engineering and Biotechnology
来源
关键词
cadmium(II); crystal structure; malate ligand; coordination polymer; two-dimension; fluorescence;
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学科分类号
摘要
A new two-dimensional layered cadmium coordination polymer [Cd(D,L-mal)H2O]n (H2mal = malic acid) is solvothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Each Cd(II) centre is surrounded by seven oxygen atoms from three different malate ligands and one coordinated water molecular forming a pentagonal bipyramidal configuration. Furthermore, complex 1 exhibits blue intense photoluminescence property at room temperature.
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页码:1195 / 1200
页数:5
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