Carbon nanotubes supported oxygen reduction reaction catalysts: role of inner tubes

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作者
Tian Tian
Yi Cheng
Zhenfan Sun
Kai Huang
Ming Lei
Haolin Tang
机构
[1] Wuhan University of Technology,State Key Laboratory of Advanced Technology for Materials Synthesis and Processing
[2] Central South University,Hunan Provincial Key Laboratory of Nonferrous Value
[3] Hainan Vocational University of Science and Technology,Added Metallurgy
[4] Beijing University of Posts and Telecommunications,Key Laboratory of Medicinal and Edible Plants Resources of Hainan Province
关键词
Carbon nanotubes; Oxygen reduction reaction; Cobalt phthalocyanine; Pt; Number of walls;
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摘要
Carbon nanotubes (CNTs) have been widely investigated to develop efficient ORR catalysts. Here we demonstrate that CNTs with 2–7 inner tubes are better supports to develop highly efficient ORR catalysts. Macrocyclic compounds and metal particle loading can dramatically improve the activity for ORR, and the CNTs composed of 2–7 inner tubes functionalized with cobalt phthalocyanine (CoPc) or supported with Pt nanoparticles (NPs) universally demonstrated better activity for ORR, demonstrating that CNTs composed of between 2 and 7 concentric tubes were proved the best supports to develop CNT hybrids for ORR in alkaline condition. The new discovery provides guidance to develop highly efficient catalysts by selecting carbon nanotubes as supports.
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