Polymerization of butadiene during the action of the catalytic system neodymium versatate-diisobutylaluminum hydride-hexachloro-p-xylene

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作者
I. I. Salakhov
I. G. Akhmetov
V. G. Kozlov
机构
[1] OAO Nizhnekamskneftekhim,Institute of Ecology of the Volga River Basin
[2] Russian Academy of Sciences,undefined
来源
Polymer Science Series B | 2011年 / 53卷
关键词
Polymer Science Series; Catalytic System; Butadiene; Chain Termination; Monomer Conversion;
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摘要
The polymerization of butadiene in the presence of the neodymium versatate-diisobutylaluminum hydride-hexachloro-p-xylene catalytic system is studied. Quantitative information on the kinetic parameters of the process is obtained. The effects of the monomer concentration, the catalyst, and temperature on the molecular-mass characteristics and microstructure of PB are studied.
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