Thermodynamic properties of certain acetylenic peroxy derivatives of o-and m-carboranes

被引:0
|
作者
V. N. Dibrivnii
机构
[1] Lvivska Politechnika National University,
来源
Russian Journal of General Chemistry | 2006年 / 76卷
关键词
Combustion; Gibbs Energy; General Chemistry; Peroxy; Boron Carbide;
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学科分类号
摘要
Temperature dependences of heat capacity of seven peroxy-containing o-and m-carborane derivatives were determined for the first time. The entropies and Gibbs energies of formation of these compounds were calculated. The enthalpies, entropies, and Gibbs energies of meta-para transitions were determined for two pairs of isomers in the condensed and gas phases.
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页码:1085 / 1089
页数:4
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