Magnetic and Mössbauer Studies of Quaternary Argentine Loessic Soils and Paleosols

This paper is a review of the current status about the remaining problems that are found in the investigation of the Quaternary Argentine soils and loessic sediments, and the way that Mössbauer studies can assist in solving them. There are two main types of investigations that make use of the magnetic response of the samples to correlate them with information gathered by other methods. On the one hand, there is the stratigraphic and chronological research, which is of importance from the geological and paleontological points of view. On the other hand, the paleoclimatic records, of significance toward a possible model of the past climate, are also studied because of their close relation to the sediments history. However, there is not yet a model that can tell the difference between the modifications due to the climatic conditions at the time when the soils were buried from processes that occurred after burial. Some examples are given that show that Mössbauer studies can be applied with a certain degree of success when cross-checked with magnetic measurements toward understanding the processes that occurred in alluvial B (paleosols) and C horizons (loess) from the eastern part of Buenos Aires Province. Although the application of Mössbauer studies to hydromorphic processes in soils is not straightforward, there are cases in which Mössbauer spectroscopy, if applied properly and correlated with other techniques, is able to characterize the type of iron oxides existing in the materials and thus assist theories about its origin and history.