Effect of Inert Micro- and Nanoparticles on the Parameters of Detonation Waves in Silane/Hydrogen–Air Mixtures

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作者
D. A. Tropin
A. V. Fedorov
机构
[1] Russian Academy of Sciences,Khristianovich Institute of Theoretical and Applied Mechanics, Siberian Branch
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关键词
detonation suppression; silane/hydrogen composite mixtures; detailed chemical kinetics; mathematical modeling; gas suspension; nanoparticles;
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摘要
Physicomathematical modeling of interaction of detonation waves in silane/hydrogen composite mixtures with clouds of inert micro- and nanoparticles ranging from 10 nm to 100 µm is performed. The normalized detonation velocity is calculated as a function of the volume concentration of particles. It is found that the efficiency of detonation suppression increases only as the particle diameter decreases to 1 µm. The influence of the thermodynamic parameters of particles on the detonation suppression efficiency is identified. The concentration limits of detonation are determined. It is demonstrated that a certain equilibrium asymptotic level of the concentration limits of detonation is reached as the particle diameter decreases below 1 µm. An approximation of the concentration limits of detonation is obtained in the form of an analytical dependence of the limiting volume concentration of particles on their diameter and fuel concentration in a composite two-fuel mixture of silane, hydrogen, and air.
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页码:230 / 236
页数:6
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