Composition of Vapor and Liquid Phases in the Potassium Hydroxide + Methanol Reaction System at 25 °C

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作者
Andrew Y. Platonov
Alexander V. Kurzin
Andrey N. Evdokimov
机构
[1] Saint-Petersburg State Technological University of Plant Polymers (SPSTUPP–SPbGTURP),Organic Chemistry Department, Faculty of Chemical Technology
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Potassium hydroxide; Methanol; Potassium methoxide; Vapor-liquid equilibrium;
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摘要
The composition of the vapor and liquid phases of the KOH + CH3OH system has been studied by the gas chromatography (GC) method at 25 °C. It has been found that the methanol vapor concentration, and the quantity of potassium methoxide formed as a result of the acid–base reaction of potassium hydroxide with methanol, both depend on the KOH/CH3OH mole ratio. The maximum mass fraction of potassium methoxide that forms is 2.6% at the mole ratio 0.018.
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页码:335 / 342
页数:7
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