Stability of complexes of alkali metal cations with p-tert-butylcalix[4]arene-tetrakis (N, N-dimethylthioacetamide) in nitrobenzene saturated with water

被引：0

作者：

E. Makrlík

P. Vaňura

机构：

[1] University of West Bohemia,Faculty of Applied Sciences

[2] Prague Institute of Chemical Technology,undefined

来源：

Journal of Radioanalytical and Nuclear Chemistry | 2008年 / 275卷

关键词：

Stability Constant; Nitrobenzene; Acetamide; Alkali Metal Cation; Nitrobenzene Solution;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq)+NaL+(nb)⇔ML+(nb)+Na+(aq) taking place in the two-phase water-nitrobenzene system [M+=Li+, K+, Rb+, Cs+; L = p-tert-butylcalix[4]arene-tetrakis (N, N-dimethylthioacetamide); aq = aqueous phase, nb = nitrobenzene phase] were evaluated. Furthermore, the stability constants of the ML+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the cation order Cs+<Rb+<K+<Li+<Na+.

引用

页码：217 / 220

页数：3

共 50 条

[1] Stability of complexes of alkali metal cations with p-tert-butylcalix[4]arene-tetrakis (N, N-dimethylthioacetamide) in nitrobenzene saturated with water
Makrlik, E.
Vanura, P.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2008, 275 (01) : 217 - 220
[2] Stability and Probable Structure of Protonated p-tert-Butylcalix[4]arene-tetrakis(N,N-dimethylthioacetamide)
Makrlik, E.
Dybal, J.
Vanura, P.
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2009, 223 (06): : 713 - 718
[3] A proton complex of p-tert-butylcalix[4]arene-tetrakis (N,N-dimethylthioacetamide):: NMR evidence and probable structure
Kriz, Jaroslav
Dybal, Jiri
Makrlik, Emanuel
Vanura, Petr
Lang, Jan
SUPRAMOLECULAR CHEMISTRY, 2007, 19 (06) : 419 - 424
[4] Contribution to the Complexation of Some Univalent Metal Cations with p-Tert-Butylcalix[4]arene-Tetrakis(N,N-Diethylacetamide) in Nitrobenzene Saturated with Water
Makrlik, E.
Budka, J.
Vanura, P.
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2011, 225 (02): : 271 - 276
[5] Stability of the p-tert-butylcalix[4]arene-tetrakis (N, N-diethylacetamide)-hydrogen cation complex in water saturated nitrobenzene
Makrlík E.
Vaňura P.
Journal of Radioanalytical and Nuclear Chemistry, 2006, 268 (1) : 163 - 165
[6] Stability of the p-tert-butylcalix[4]arene-tetrakis (N, N-diethylacetamide)-hydrogen cation complex in water saturated nitrobenzene
Makrlík, E
Vanura, P
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2006, 268 (01) : 163 - 165
[7] Stability of the ammonium-p-tert-butylcalix[4]arene-tetrakis (N,N-diethylacetamide) complex in nitrobenzene saturated with water
Makrlík, E
Venura, P
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2006, 267 (03) : 711 - 713
[8] Stability of the ammonium-p-tert-butylcalix[4]arene-tetrakis (N,N-diethylacetamide) complex in nitrobenzene saturated with water
E. Makrlík
P. Vaňura
Journal of Radioanalytical and Nuclear Chemistry, 2006, 267 : 711 - 713
[9] Stability of complexes of alkali metal cations with tetraethyl p-tert-butylcalix[4]arene tetraacetate in the water-nitrobenzene extraction system
Makrlik, E.
Vanura, P.
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2007, 221 (07): : 881 - 886
[10] Solvent Extraction of Some Divalent Metal Cations into Nitrobenzene by Using a Synergistic Mixture of Strontium Dicarbollylcobaltate and p-tert-Butylcalix[4]arene-tetrakis (N,N-Diethylacetamide)
Makrlik, Emanuel
Budka, Jan
Vanura, Petr
Selucky, Pavel
ACTA CHIMICA SLOVENICA, 2012, 59 (04) : 934 - 938

← 1 2 3 4 5 →