Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review

被引：0

作者：

Mikhail M. Levitsky

Yan V. Zubavichus

Alexander A. Korlyukov

Victor N. Khrustalev

Elena S. Shubina

Alexey N. Bilyachenko

机构：

[1] Nesmeyanov Institute of Organoelement Compounds,

[2] Russian Academy of Sciences,undefined

[3] Boreskov Institute of Catalysis SB RAS,undefined

[4] Pirogov Russian National Research Medical University,undefined

[5] Peoples’ Friendship,undefined

[6] University of Russia,undefined

[7] (RUDN University),undefined

来源：

Journal of Cluster Science | 2019年 / 30卷

关键词：

Metallasilsesquioxanes; Metallagermsesquioxanes; Cage compounds; High-nuclearity; Single-crystal X-ray diffraction; Coordination polymers; Supramolecular design; Catalytic activity;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.

引用

页码：1283 / 1316

页数：33

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