Prediction of the Attractive Branch of the Effective Pair Potential Using the Joule–Thomson Inversion Curve

被引：0
|
作者：
E. Keshavarzi
G. Parsafar
B. Najafi
机构：
[1] Isfahan University of Technology,Department of Chemistry
来源：
International Journal of Thermophysics | 1999年 / 20卷
关键词：
effective pair potential; inversion curve; Joule–Thomson coefficient;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the present work, the attractive branch of the effective pair potential is predicted by using p–v–T data of the Joule–Thomson inversion curve. It is concluded that all loci of the thermodynamic states of the inversion curve correspond to the attractive branch of the effective pair potential. It is also predicted that the minimum of the effective pair potential well, rm, is less than that of the isolated pair potential, because the attraction term has a longer range than the repulsion term.
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页码：643 / 650
页数：7
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