Aggregation behavior and catalytic activity of systems based on calix[4]resorcinarene derivatives and surfactants. 1. Mixed micellization of aminomethylated calix[4]resorcinarenes with cetyltrimethylammonium bromide in aqueous dimethylformamide

被引：0
|
作者：
I. S. Ryzhkina
T. N. Pashirova
L. A. Filippova
A. P. Kudryavtseva
V. P. Timosheva
Z. Sh. Arkhipov
E. V. Idiyatullin
A. R. Popova
A. I. Burilov
机构：
[1] Kazan Research Center of the Russian Academy of Sciences,
[2] Kazan State Technological University,undefined
来源：
Russian Chemical Bulletin | 2004年 / 53卷
关键词：
micellization; mixed micelles; critical micelle concentrations; amphiphilic compounds; surfactant; aminomethylated calix[4]resorcinarene; -aminomethylphenol; cetyltrimethylammonium bromide;
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学科分类号：
摘要：
Mixed micellization of amphiphilic aminomethylated calix[4]resorcinarenes and phenols, which are their structural units, with the cationic surfactant cetyltrimethylammonium bromide (CTAB) in aqueous 10—70 vol % DMF decreases the critical micelle concentration; the resulting aggregates are larger than those in the CTAB—DMF—water systems. The micellization of CTAB with aminomethylated calix[4]resorcinarenes proceeds in two steps, while its micellization with phenols is a single-step process. The micellization characteristics depend on the structure and hydrophobicity of the amphiphilic compound and the concentration of DMF.
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页码：1520 / 1527
页数：7
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