Synthesis and crystal structure of new titanyl phosphate Sr2TiO(PO4)2

被引：0
|
作者：
R. V. Shpanchenko
A. A. Tsirlin
J. Hadermann
E. V. Antipov
机构：
[1] M. V. Lomonosov Moscow State University,Department of Chemistry
[2] University of Antwerp,Electron Microscopy for Materials Science (EMAT)
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
strontium titanyl phosphate; complex transition metal phosphates; X-ray diffraction study; electron diffraction; high-resolution electron microscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New strontium titanyl phosphate Sr2TiO(PO4)2 (1) was synthesized and characterized by X-ray powder diffraction, electron diffraction, high-resolution electron microscopy, and band structure calculations. Titanyl phosphate 1 is isostructural with vanadyl phosphate Sr2VO(PO4)2 and has a layered structure. The titanium atoms are shifted from the centers of the TiO6 octahedra and form short (1.74 Å) titanyl bonds. The structure of 1 is an unusual example of the disordered orientation of the chains formed by TiO6 octahedra in complex titanium phosphates.
引用
收藏
页码：552 / 556
页数：4
相关论文
共 50 条
  • [1] Synthesis and crystal structure of new titanyl phosphate Sr2TiO(PO4)2
    Shpanchenko, R. V.
    Tsirlin, A. A.
    Hadermann, J.
    Antipov, E. V.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (03) : 552 - 556
  • [2] Synthesis and structure of a strontium vanadyl phosphate: Sr2(VO)(PO4)2
    Wadewitz, C.
    Müller-Buschbaum, Hk.
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996, 51 (07): : 929 - 933
  • [3] Synthesis and structure of a strontium vanadyl phosphate: Sr-2(VO)(PO4)(2)
    Wadewitz, C
    MullerBuschbaum, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (07): : 929 - 933
  • [4] Synthesis, crystal structure, and ionic conductivity of a new layered metal phosphate, Li2Sr2Al(PO4)3
    Kim, Sung-Chul
    Kwak, Hyun-Jung
    Yoo, Chung-Yul
    Yun, Hoseop
    Kim, Seung-Joo
    JOURNAL OF SOLID STATE CHEMISTRY, 2016, 243 : 12 - 17
  • [5] Synthesis and structure of Sr2Co(PO4)2
    Belik, AA
    Lazoryak, BI
    Terekhina, TP
    Polyakov, SN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2001, 46 (09) : 1312 - 1318
  • [6] RbZnFe(PO4)(2): synthesis and crystal structure
    Badri, Abdessalem
    Ben Amara, Mongi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1074 - +
  • [7] Synthesis and structure of Sr2Co(PO4)2
    Belik, A.A.
    Lazoryak, B.I.
    Terekhina, T.P.
    Polyakov, S.N.
    Zhurnal Neorganicheskoj Khimii, 2001, 46 (09): : 1453 - 1460
  • [8] Synthesis and crystal structure of CsNb(PO4)2
    Murashova, EV
    Chudinova, NN
    CRYSTALLOGRAPHY REPORTS, 1999, 44 (06) : 955 - 957
  • [9] Synthesis and crystal structure of NaCuIn(PO4)2
    Benhsina, Elhassan
    Khmiyas, Jamal
    Ouaatta, Said
    Assani, Abderrazzak
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 366 - +
  • [10] Synthesis, Crystal Structure and Properties of a New Phosphate, Na2Co2Cr(PO4)3
    Hadouchi, Mohammed
    Assani, Abderrazzak
    Saadi, Mohamed
    Saadoune, Ismael
    Lahmar, Abdelilah
    Bouyanfif, Houssny
    El Marssi, Mimoun
    El Ammari, Lahcen
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2018, 28 (06) : 2854 - 2864
12345