Formation of Anatase Nanocrystals in Sol-Gel Derived TiO2-SiO2 Thin Films with Hot Water Treatment

被引：13
|
作者：
Yoshinori Kotani
Atsunori Matsuda
Masahiro Tatsumisago
Tsutomu Minami
Taku Umezawa
Toshihiro Kogure
机构：
[1] Osaka Prefecture University,Department of Applied Materials Science, Graduate School of Engineering
[2] Sakai,Department of Applied Materials Science, Graduate School of Engineering
[3] Osaka Prefecture University,Mineralogical Institute, Graduate School of Science
[4] Sakai,undefined
[5] The University of Tokyo,undefined
来源：
Journal of Sol-Gel Science and Technology | 2000年 / 19卷
关键词：
anatase; nanocrystals; hot water treatment; poly(ethylene glycol); TiO; -SiO;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We have successfully prepared transparent and porous anatase nanocrystals-dispersed films by treating the sol-gel derived TiO2-SiO2 films containing poly(ethylene glycol), PEG, with hot water. This process was done at temperatures lower than 100°C under atmospheric pressure, and thus anatase nanocrystals-dispersed films can be formed on various kinds of substrates including organic polymers with poor heat resistance. The changes in structure and composition of the TiO2-SiO2 gel films with hot water treatment were related to the formation process of anatase nanocrystals in the TiO2-SiO2 gel films with hot water treatment. The formation of anatase nanocrystals was found to proceed to hydrolysis of Si–O–Ti bonds and dissolution of SiO2 component. In addition, porous film structure formed by leaching of PEG with hot water treatment led to homogenous dispersion of anatase nonocrystals in the films.
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页码：585 / 588
页数：3
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