Improvement of Chromium(VI) Extraction from Acidic Solutions Using a Poly(vinyl chloride)-based Polymer Inclusion Membrane with Aliquat 336 as the Carrier

被引:0
|
作者
Shigehiro Kagaya
Tomonori Maeno
Kazuma Ito
Makoto Gemmei-Ide
Robert W. Cattrall
Spas D. Kolev
机构
[1] University of Toyama,Graduate School of Science and Engineering for Research
[2] School of Chemistry,undefined
[3] The University of Melbourne,undefined
来源
Analytical Sciences | 2017年 / 33卷
关键词
Polymer inclusion membrane; poly(vinyl chloride); Aliquat 336; chromium(VI); extraction; sodium nitrate;
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学科分类号
摘要
An important reason for the inefficient extraction of Cr(VI) from its acidic solutions into polymer inclusion membranes (PIMs), consisting of poly(vinyl chloride) as the base-polymer and Aliquat 336 as the carrier, was found to be associated with the leaching of Aliquat 336 from the PIMs into the solutions, where it subsequently reduced the anionic Cr(VI) species to cationic Cr(III) species. The PIM extraction efficiency for Cr(VI) was significantly improved by the addition of NaNO3 to the solutions, which suppressed the leaching of Aliquat 336 and the reduction of Cr(VI) to Cr(III).
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页码:643 / 646
页数:3
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