Synthesis and study of electrochemical properties of nanocomposites with graphene-like particles integrated into a high-porosity carbon matrix

被引:0
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作者
Yu. G. Kryazhev
Yu. M. Volfkovich
V. P. Mel’nikov
A. Yu. Rychagov
M. V. Trenikhin
V. S. Solodovnichenko
E. S. Zapevalova
V. A. Likholobov
机构
[1] Russian Academy of Sciences,Institute of Hydrocarbons Processing, Siberian Branch
[2] Russian Academy of Sciences,A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
[3] Russian Academy of Science,Semenov Institute of Chemical Physics
[4] Russian Academy of Sciences,Omsk Scientific Center, Siberian Branch
关键词
chloropolymers; nanocomposites; nanoparticles; carbon; graphene-like structures; supercapacitors;
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摘要
Carbon–carbon nanocomposite (CCNC) was synthesized by introducing a dispersion of reduced graphite oxide (RGO) into the reaction medium upon the synthesis of polymer with a conjugated bond system (polyvinylene), which is a product of alkaline dehydrochlorination of polyvinylchloride, followed by carbonization of the resulting adduct–RGO-polyvinylene. After activation of CCNC in the CO2 environment (900°С) a high-porosity material (the specific BET surface is more than 1700 m2/g) with a developed volume of micro- and mesopores was obtained. According to electrochemical investigations, this material possesses a large capacity (100–200 F/g) and high performance, and, therefore, it can be applied in supercapacitor traction systems and for load leveling in electric power lines.
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页码:422 / 425
页数:3
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