Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure

被引:0
|
作者
A. S. Zaguzin
D. V. Spiridonova
A. S. Novikov
M. I. Rakhmanova
D. A. Zherebtsov
V. P. Fedin
S. A. Adonin
机构
[1] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
[2] South Ural State University,Institute of Chemistry
[3] St. Petersburg State University,undefined
[4] St. Petersburg State University,undefined
来源
Russian Chemical Bulletin | 2023年 / 72卷
关键词
zinc; carboxylates; complexes; halogen bond;
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中图分类号
学科分类号
摘要
The reaction of zinc(II) nitrate with 5-iodoisophthalic acid (5-I-IPAH) in N,N-dimethylformamide afforded the layered coordination polymer {Zn(5-I-IPA)}n(1). The structure of 1 was determined by single-crystal X-ray diffraction. The phase purity of 1 was confirmed by powder X-ray diffraction. The molecular electrostatic potentials of iodine atoms, which characterize their ability to form a halogen bond, were determined by quantum chemical calculations.
引用
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页码:177 / 183
页数:6
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