Iron-catalyzed conversion of unactivated aryl halides to phenols in water

被引：30

作者：

Ren, Yunlai ^{[1
]}

Cheng, Lin ^{[1
]}

Tian, Xinzhe ^{[1
]}

Zhao, Shuang ^{[1
]}

Wang, Jianji ^{[1
]}

Hou, Chaodong ^{[1
]}

机构：

[1] Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 01期

基金：

国家高技术研究发展计划(863计划);

关键词：

Aryl halide; Iron; Water; Phenol; CROSS-COUPLING REACTIONS; O BOND FORMATION; HYDROGENATION; COMPLEXES; LIGAND; COPPER; EPOXIDATION; EFFICIENT; BEARING; KETONES;

D O I：

10.1016/j.tetlet.2009.10.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Although iron is low-cost and environmentally friendly, there is no report about iron-catalyzed conversion of unactivated aryl halides to phenols. In this Letter, a new method for the present conversion was developed with iron Compounds as the catalyst and water as the solvent. The suggested method allowed a series of unactivated aryl bromides and aryl iodides to be converted into the corresponding substituted phenols in moderate to high yields. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：43 / 45

页数：3

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