Two anionic low-connectivity microporous indium-organic frameworks with selectivity adsorption of CO2 over CH4

被引:6
|
作者
Liu, Daofu [1 ,2 ]
Wen, Gulin [1 ]
Zhou, Weiwei [1 ]
机构
[1] Huainan Normal Univ, Sch Chem & Chem Engn, Huainan, Peoples R China
[2] Anhui Univ, Sch Chem & Chem Engn, Hefei, Anhui, Peoples R China
关键词
Metal-organic framework; Anionic; Low-connectivity; Microporous; Selectivity adsorption; WHITE-LIGHT EMISSION; OPEN METAL SITES; BIOMIMETIC MINERALIZATION; GAS-ADSORPTION; SEPARATION; CATALYSIS;
D O I
10.1016/j.inoche.2018.06.023
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Up to now, the synthetic development of metal-organic frameworks (MOFs) continues to attract much attention because of their intriguing structural topologies and potential applications. Herein, two anionic low-connectivity microporous indium-organic framework materials (named complex 1 and complex 2) have been solvothermally synthesized, which were further characterized by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), elemental analysis, thermogravimetric analysis (TGA), and gas sorption in detail. In addition, complex 1 exhibits high selectivity adsorption of CO2 over CH4 at ambient conditions.
引用
收藏
页码:22 / 26
页数:5
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