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Two anionic low-connectivity microporous indium-organic frameworks with selectivity adsorption of CO2 over CH4
被引:6
|作者:
Liu, Daofu
[1
,2
]
Wen, Gulin
[1
]
Zhou, Weiwei
[1
]
机构:
[1] Huainan Normal Univ, Sch Chem & Chem Engn, Huainan, Peoples R China
[2] Anhui Univ, Sch Chem & Chem Engn, Hefei, Anhui, Peoples R China
关键词:
Metal-organic framework;
Anionic;
Low-connectivity;
Microporous;
Selectivity adsorption;
WHITE-LIGHT EMISSION;
OPEN METAL SITES;
BIOMIMETIC MINERALIZATION;
GAS-ADSORPTION;
SEPARATION;
CATALYSIS;
D O I:
10.1016/j.inoche.2018.06.023
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Up to now, the synthetic development of metal-organic frameworks (MOFs) continues to attract much attention because of their intriguing structural topologies and potential applications. Herein, two anionic low-connectivity microporous indium-organic framework materials (named complex 1 and complex 2) have been solvothermally synthesized, which were further characterized by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), elemental analysis, thermogravimetric analysis (TGA), and gas sorption in detail. In addition, complex 1 exhibits high selectivity adsorption of CO2 over CH4 at ambient conditions.
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页码:22 / 26
页数:5
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