Photoprocesses in dimers and dimeric complexes of polymethine dyes with cucurbiturils

被引：4
|
作者：
Chibisov, A. K. [1 ,2 ]
Alfimov, M., V [1 ,2 ]
Zakharova, G., V [1 ]
Avakyan, V. G. [1 ,2 ]
Fedotova, T., V [1 ,2 ]
Gutrov, V. N. [1 ]
机构：
[1] Russian Acad Sci, Photochem Ctr, Fed Sci Res Ctr Crystallog & Photon, Build 1,7a Ul Novatorov, Moscow 119421, Russia
[2] Moscow Inst Phys & Technol, 9 Inst Skiy Per, Dolgoprudnyi 141701, Moscow Region, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 02期
关键词：
polymethine dyes; cucurbiturils; complexation; absorption; fluorescence; triplet-triplet absorption; triplet-triplet energy transfer; electron transfer; quantum chemical calculations; ELECTRON-TRANSFER; THIACARBOCYANINE DYES; CYANINE DYES; ELECTROLUMINESCENCE; THERMODYNAMICS; DIMERIZATION; AGGREGATION; MONOMERS; ENERGY; STATES;
D O I：
10.1007/s11172-022-3398-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The review is devoted to the structure and photoprocesses in dimers of polymethine dyes and their complexes as objects of supramolecular photochemistry. The results of studies on the structure of dimers and dimeric complexes with cucurbiturils obtained from quantum chemical calculations are presented. The spectral-luminescent properties of dimers and approaches to their origin are considered. Data on the triplet states of dimers and dimeric complexes are presented. The results of studies on triplet-triplet energy transfer, electron phototransfer in redox reactions of dimers, and photosensitized oxidation reaction are analyzed.
引用
收藏
页码：199 / 211
页数：13
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