Is there really a diagnostically useful relationship between the carbon-oxygen stretching frequencies in metal carboxylate complexes and their coordination mode?

被引：54

作者：

Martinez, David ^{[1
]}

Motevalli, Majid ^{[1
]}

Watkinson, Michael ^{[1
]}

机构：

[1] Queen Mary Univ London, Sch Biol & Chem Sci, London E1 4NS, England

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

SCHIFF-BASE LIGANDS; MANGANESE(III) COMPLEXES; CRYSTAL; EPOXIDATION; CHLORIDE;

D O I：

10.1039/b913865j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An investigation into the relationship between the asymmetric and symmetric stretching modes of ancillary carboxylate ligands and their mode of binding in a family of manganese(III) complexes of tetradentate N2O2 Schiff base ligands, which includes comparison of an O-18 isotopically labelled derivative, has been undertaken. The results suggest that caution should be employed in using this technique to assign the binding mode of the carboxylate ligands in these complexes despite its very extensive use in the literature.

引用

页码：446 / 455

页数：10

共 8 条

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