A facile photosynthesis of trans-dioxoruthenium(VI) porphyrins

被引：17
|
作者：
Huang, Yan [1 ]
Vanover, Eric [1 ]
Zhang, Rui [1 ]
机构：
[1] Western Kentucky Univ, Dept Chem, Bowling Green, KY 42101 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 21期
关键词：
FLASH-PHOTOLYSIS GENERATION; ENANTIOSELECTIVE ALKENE EPOXIDATION; C-H BOND; ASYMMETRIC EPOXIDATION; RUTHENIUM PORPHYRIN; RATE CONSTANTS; COMPLEXES; OXO; OXIDATION; INTERMEDIATE;
D O I：
10.1039/c003094e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photolysis of porphyrin-ruthenium(IV) dichlorate complexes with visible light results in homolytic cleavage of the O-Cl bond in the chlorates to form trans-dioxoruthenium(VI) species bearing either sterically encumbered or unencumbered porphyrin ligands.
引用
收藏
页码：3776 / 3778
页数：3
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