OPTIMIZATION OF THE EPOXIDATION OF METHYL ESTER OF PALM FATTY ACID DISTILLATE

被引：0
|
作者：
Lee, P. L. [1 ]
Yunus, W. M. Z. Wan [1 ]
Yeong, S. K. [2 ]
Abdullah, Dzulkefly Kuang [1 ]
Lim, W. H. [2 ]
机构：
[1] Univ Putra Malaysia, Dept Chem, Fac Sci, Serdang 43400, Selangor, Malaysia
[2] Malaysian Palm Oil Board, Kuala Lumpur 50720, Malaysia
来源：
JOURNAL OF OIL PALM RESEARCH | 2009年 / 21卷
关键词：
epoxidation; palm fatty acid distillate; hydrogen peroxide; epoxidized vegetable oil; PARAMETERS; OILS;
D O I：
暂无
中图分类号：
TS2 [食品工业];
学科分类号：
0832 ;
摘要：
Methyl ester of palm fatty acid distillate (PFAD-ME) can be used for producing epoxide compounds. RFAD-ME consists of 39.3% of oleic acid (C18:1) and has an iodine value of 49.2 g I-2/100 g. It can be converted to a low oxirane content epoxide which can be used for several applications, such as plasticizers, polyols or alkanolamines, with appropriate modification. Temperature, mole ratio of hydrogen peroxide to unsaturation, and mole ratio of formic acid to unsaturation were optimized in the epoxidation of PFAD-ME. The study showed that more than 98% conversion of unsaturation to the epoxide ring moiety can be achieved within 3 hr of reaction by using the optimum molar ratio of 1:1:4 (unsaturation: formic acid: hydrogen peroxide) and a temperature of 50 degrees C.
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收藏
页码：675 / 682
页数：8
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